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Odor Control and Odor Thresholds

Civil Engineering and Design

Odor Control and Odor Thresholds for Human Smell

Ventilation engineering:

(1) contemporary construction methods result in buildings that allow less air infiltration through the building envelope;
(2) indoor sources of odors associated with modern building materials, furnishings, and office equipment have increased;
(3) outdoor air is often polluted; and
(4) energy costs encourage lower ventilation rates at a time when requirements for a relatively odor-free environment are greater than ever.

Outdoor odor sources that may require engineering mitigation are:

  • automotive exhaust
  • diesel exhaust
  • hazardous waste sites
  • sewage treatment plants
  • compost piles
  • refuse facilities
  • printing plants
  • refineries
  • chemical plants

indoor odor sources include

  • tobacco products
  • bathrooms and toilets
  • building materials
    • (e.g., adhesives,
    • paints,
    • caulks,
    • processed wood,
    • carpets,
    • plastic sheeting,
    • insulation board),
  • consumer products (e.g., food, toiletries, cleaning materials, polishes),
  • hobby materials,
  • fabrics,
  • foam cushions.
  • offset printing processes,
  • copiers,
  • computer printers
  • Electrostatic processes may emit ozone.
  • Humans emit a wide range of odorant's
    • acetaldehyde,
    • ammonia,
    • ethanol,
      hydrogen sulfide,
    • mercaptans.
  • Mildew and other decay processes often produce odors in occupied
    spaces (home and office),
  • damp basements,
  • ventilation systems (e.g., from wetted air-conditioning coils and spray dehumidifiers).

The table below shows odor detection threshold concentrations for selected compounds. The threshold limit value (TLV) is the concentration of a compound that should have no adverse health consequences if a worker is regularly exposed for 8 h periods (ACGIH, revised annually). For ratios greater than 1, most occupants can detect the odor and leave the area long before the compound becomes a health risk. As the ratio increases, the safety factor provided by the odor also increases.

Compound
Odor Threshold,a
ppmv
TLV,b
ppmv
Ratio
Acetaldehyde
0.067
25-C
360
Acetone
62
500
8.1
Acetonitrile
1600
20
0.013
Acrolein
1.8
0.1-C
0.06
Ammonia
17
25
1.5
Benzene
61
0.5
0.01
Benzyl chloride
0.041
1
24
Carbon tetrachloride
250
5
0.02
Chlorine
0.08
0.5
6
Chloroform
192
10
0.05
Dioxane
12
20
1.7
Ethylene dichloride
26
10
0.4
Hydrogen sulfide
0.0094
10
1064
Methanol
160
200
1.25
Methylene chloride
160
50
0.3
Methyl ethyl ketone
16
200
12.5
Phenol
0.06
5
83
Sulfur dioxide
2.7
2
0.74
Tetrachloroethane
7.3
1
0.14
Tetrachloroethylene
47
25
0.5
Toluene
1.6
20
13
Trichloroethylene
82
10
0.1
Xylene (isomers)
20
100
5

Sources: ACGIH (updated annually), AIHA (1989).

aAll thresholds are detection thresholds (ED50).
bAll TLVs are 8 h time-weighted averages, except those shown with -C, which are 15 min ceiling values.

Source

ASHRAE Handbook, I-P Eidtion 2021

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